A lot of the tests you're thinking of (most of the possible vitamin/mineral tests) are probably not going to be covered by insurance, and may be expensive, inaccurate, or unavailable. Minerals, for example, are hard to get a good read on. Do you have any reason to believe that you are suffering from a fluoride toxicity?
I don't know whether it's justified, but there is a lot of buzz about using fluoride-based toothpaste. Obviously I shouldn't really worry, given that it's a pretty much universal ingredient in toothpastes. But I do know that some mineral toxicities could underlie ADHD symptoms and there was a time in the past where I used to brush rather obsessively and would often eat shortly thereafter. This isn't anything that I've really done much research on.
I thought I should mention that I live in Canada, despite my 'location' information, so I hope that coverage isn't an issue.
Hb A1c will tell you how good your glucose control has been over the past three months or so. Lower is better. If you can get it under 5% that's great.
I actually had it in mind a few months ago to test my glucose metabolism. I am not sure if I am dysfunctional in that regard, but I tend to get migraines if I don't eat anything for about 2-3 hours (even if after a big meal), I am compelled to eat very frequently (though this might be because I tend to eat small meals, mostly of fruits), and that I would often feel very tired after big meals (though I suppose I forgot about this since it went away once I started taking ritalin). But I decided against the test, since I had read that such a test would require fasting for an extended period of time. And of course, given my inability to fast without getting a migraine, I decided against it.
I'm not sure if the test you suggested has the same requirement or has anything at all to do with the problems I listed, but I just thought I would throw that in there. I definitely will do some research on it and I really appreciate the suggestion.
You should probably be supplementing D3; I recommend 2000 IU of an oil-based (softgel) formulation. Dry forms are poorly absorbed. I shoot for 40-50 ng/ml.
I occasionally do supplement D3 (and used to regularly take cod liver oil), but no where near those doses. Is there any reason to supplement that much? IIRC, there's a thread floating around here (that I only skimmed, mind you) about some recent research that warns against D3 megadosing. But I might be thinking of something else.