I have about the same problem as you, my room is filled up with electronic devices whom I suspect my computer fan to damage ambient air quality.
I think the smell is due to heated up air coming out of the computer and not because oxygen is decreasing.
If we extrapolate, we can say that computer generate hot air, hot air causes dilation of your vessels and opens up your pores which causes toxin release, it might be farfetched to say toxins are responsible of the smell but my experience tells me it could be true. (in winter I don't get that as opposed to spring and summer)
Anyway concerning oxygen don't worry about it there's plenty enough and your computer isn't depleting your room of oxygen.
But I would advise to open up your windows once a day for 10 minutes.
What you are worried about is a thing called "outgassing" the interior of cars do it aswell, which causes the scent of "new car smell".
What you DO NOT want to be breathing in is hot or overheated (ie, from cheap electronics) LEAD and mercury vapours.
Compact Fluorescents will give off lead vapours aswell, but the mercury vapours are enclosed inside of the glass, what you DO NOT want to happen however is for you to crack this glass while it is turned on, or even if its turned off, as the mercury vapor, even a small amount will get into the air of your room and eventually cover a large portion of your carpet or wherever it landed onto.
The best method of cleaning up mercury vapor spills is with baby wipes or with a wet tea towel and a dust broom, while you are wearing gloves, DO NOT VACUUM as that will spread the mercury EVERYWHERE.
And the contents inside of electrolytic capacitors are toxic aswell, they vent very gradually as they age, however if the electronic device is cheaply made then it will vent them much faster.
Dont ever damage or destroy CRT television sets or monitors inside of your home or even outside either, as they contain an even larger amount of mercury vapor, hell even the outside of the picture tube/CRT tube is coated in a thin layer of lead powder.
I would recommend that you keep a window slightly open or ajar for a predetermined period of time during the day and to lock it in place with a sturdy window lock so theives cannot jump in and steal your stuff..
Its either that or buying a proper room air cleaner with a HEPA grade paper filter and a charcoal bag filter and leaving that on all of the time or only a couple of hours a day or night.
Edited by Layberinthius, 17 November 2013 - 04:34 AM.